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Versatile Coordination of Ag I and Cu I Ions towards cyclo ‐As 5 Ligands

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Moussa, Mehdi Elsayed ; Fleischmann, Martin ; Balázs, Gábor ; Virovets, Alexander V. ; Peresypkina, Eugenia V. ; Shelyganov, Pavel A. ; Seidl, Michael ; Reichl, Stephan ; Scheer, Manfred
License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 08 Jun 2021 05:37

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The reactions of the cyclo-As-5 complex [Cp*Fe(eta(5)-As-5)] (B) with the Ag-I and Cu-I salts of the weakly coordinating anion (WCA) [FAl{OC6F10(C6F5)}(3)](-) ([FAl](-)) are studied. These reactions allow the synthesis of the mononuclear complexes [M(eta(5) : eta(2)-B)(2)][FAl] (M=Ag (1), Cu (2)) when a ratio of B/M(FAl) 2 : 1 is used. Compound 1 shows an unusual disorder of the central Ag-I ...


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