Versatile Coordination of Ag I and Cu I Ions towards cyclo ‐As 5 Ligands

URN to cite this document:: urn:nbn:de:bvb:355-epub-459370
DOI to cite this document:: 10.5283/epub.45937

Moussa, Mehdi Elsayed ; Fleischmann, Martin ; Balázs, Gábor ; Virovets, Alexander V. ; Peresypkina, Eugenia V. ; Shelyganov, Pavel A. ; Seidl, Michael ; Reichl, Stephan ; Scheer, Manfred

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Date of publication of this fulltext: 08 Jun 2021 05:37

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Abstract

The reactions of the cyclo-As5 complex [Cp*Fe(η5-As5)] (B) with the AgI and CuI salts of the weakly coordinating anion (WCA) [FAl{OC6F10(C6F5)}3]− ([FAl]−) are studied. These reactions allow the synthesis of the mononuclear complexes [M(η5 : η2-B)2][FAl] (M=Ag (1), Cu (2)) when a ratio of B/M(FAl) 2 : 1 is used. Compound 1 shows an unusual disorder of the central AgI cation between two ...