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High-Perfomance thermoelectrics from cellular nanostructured Sb2Si2Te6

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Luo, Y. ; Cai, S. ; Hao, S. ; Pielnhofer, F. ; Hadar, I. ; Luo, Z.-Z. ; Xu, J. ; Wolverton, C. ; Dravid, V. P. ; Pfitzner, Arno ; Yan, Q. ; Kanatzidis, M. G.
Date of publication of this fulltext: 29 Jun 2021 07:25


We introduce Sb2Si2Te6 as a high-performance thermoelectric material. Single-crystal X-ray diffraction analysis indicates that Sb2Si2Te6 has a layered two-dimensional structure with Sb3+ cations and [Si2Te6](6) units as building blocks adopting the Fe2P2Se6 structure type. Sb2Si2Te6 is a direct-band-gap semiconductor with valence-band maximum and conduction-band minimum at the Z point in the ...


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