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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-462918
- DOI to cite this document:
- 10.5283/epub.46291
This publication is part of the DEAL contract with Wiley.
Abstract
The reaction of [Cp ''' Ni(eta(3)-P-3)] (1) with in situ generated phosphenium ions [RR ' P](+) yields the unprecedented polyphosphorus cations of the type [Cp ''' Ni(eta(3)-P4R2)][X] (R=Ph (2 a), Mes (2 b), Cy (2 c), 2,2 '-biphen (2 d), Me (2 e); [X](-)=[OTf](-), [SbF6](-), [GaCl4](-), [BArF](-), [TEF](-)) and [Cp ''' Ni(eta(3)-P4RCl)][TEF] (R=Ph (2 f), tBu (2 g)). In the reaction of 1 with ...
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