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Tuning the dimensionality of organometallic–organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions

Elsayed Moussa, Mehdi ; Peresypkina, Eugenia ; Virovets, Alexander V. ; Venus, Dominik ; Balázs, Gábor ; Scheer, Manfred


The reactions of the P-2 ligand complex [Cp2Mo2(CO)(4)(eta(2)-P-2)] (Cp = C5H5, 1) with Ag[Al{OC(CF3)(3)}(4)] (Ag[TEF]) in the presence of the rigid bipyridyl linkers 1,2-di(pyridin-4-yl)ethyne (3), 4,4'-bis(pyridin-4-ylethynyl)-1,1'-biphenyl (4) and 4,4'-bipyridine (5) possessing various lengths are studied. The reaction with the longer linkers (3 and 4) leads to the formation of the 1D ...


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