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Highly soluble Cu(i)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds

Elsayed Moussa, Mehdi ; Piesch, Martin ; Fleischmann, Martin ; Schreiner, Andrea ; Seidl, Michael ; Scheer, Manfred


The synthesis of the air-stable and highly soluble Cu(I-acetonitrile salts [Cu(CH3CN)(3.5)][FAL] (1) ([FAL] = FAL{OC(C6F10)(C6F5)}(3)) and [Cu(CH3CN)(4)][TEF] (2) ([TEF] = Al{OC(CF3)(3)}(4)) is presented. Compound 1 reacts with the organometallic polyphosphorus complexes [Cp2Mo2(CO)(4)(eta(2)-P-2)] (A) and [(Cp*Fe(eta(5)-P-5)] (B) and salt 2 reacts with B to form one new (3) and three ...


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