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CdBiO2NO3, a new layered bismuth oxide nitrate

Charkin, D. O. ; Plokhikh, I. V. ; Zadoya, A. I. ; Kuznetsova, P. L. ; Kazakov, S. M. ; Siidra, O. I.


Step-wise reaction of CdO, Bi2O3, and Cd(NO3)(2)center dot 4H(2)O leads to formation of a novel bismuth oxide nitrate, CdBiO2NO3, which completes the family of bis-muthite-like (MBiO2NO3)-Bi-II oxide nitrates. The new compound is tetragonal, I4/mmm, a = 3.9486(1)angstrom, c = 14.2235(2)angstrom; its crystal structure resembles those of PbBiO2NO3 and CdBiO2NO3, except for, probably, different ...


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