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The Chirality Chain in Valine: How the Configuration at the C α Position through the O cis C′C α N Torsional System Leads to Distortion of the Planar Group C α C′(O cis )O trans to a Flat Tetrahedron

Brunner, Henri ; Tsuno, Takashi



Abstract

Solid-state structures, based on a Cambridge Structural Data-base (CSD) search, show that there is a C alpha N/C'O-cis attraction in the torsional system OcisC'C alpha N of valine, causing a chirality chain. The C-alpha configuration controls the chirality of the rotation around the C'-C-alpha bond, which in turn induces a distortion of the planar unit C alpha C'(O)O to a flat asymmetric ...

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