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Element-specific magnetic properties of mixed 3d−4f metallacrowns

Alhassanat, A. ; Gamer, C. ; Rauguth, A. ; Athanasopoulou, A. A. ; Sutter, J. ; Luo, C. ; Ryll, H. ; Radu, F. ; Sapozhnik, A. A. ; Mashoff, T. ; Rentschler, E. ; Elmers, H. J.


Single molecule magnets comprising rare earth metals are of high interest due to the unquenched orbital moments of the rare earth ions that result in a large energy barrier for magnetization reversal. We investigate the magnetic properties of polynuclear 3d-4f 15-MC-5 metallacrowns using x-ray magnetic circular dichroism of powder samples at a temperature of 7 K in a magnetic field of 7 T. The ...


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