Go to content
UR Home

Synthesis, electronic structure and redox properties of the diruthenium sandwich complexes [Cp*Ru(μ-C10H8)RuCp*]x (x = 0, 1+; Cp* = C5Me5; C10H8 = naphthalene)

Herrmann, Dirk ; Rödl, Christian ; de Bruin, Bas ; Hartl, František ; Wolf, Robert


The dinuclear ruthenium complex [Cp*Ru(-C10H8)RuCp*] (1; Cp* = (5)-C5Me5) was prepared by reduction of the cationic precursor [Cp*Ru((6)-C10H8)]PF6 with KC8. Diamagnetic 1 has a symmetric molecular structure with an anti-facial configuration of the Cp*Ru moieties coordinating to naphthalene. Density Functional Theory (DFT) studies showed an electronic structure similar to that of the analogous ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons