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En Route to Bis-Carbene Analogues of the Heavier Group 13 Elements: Consideration of Bridging Group and Metal(I) Source

Desat, Marcella E. ; Kretschmer, Robert


With the aim of exploring the effect of steric constraints imposed on the metal-metal interaction of bis-carbene analogues of thallium by the linking scaffold, seven dinuclear thallium diyls with a series of rigid, semirigid, and flexible bridging scaffolds were synthesized. The solid-state molecular structures were determined for four of these compounds by single-crystal XRD and compared with ...


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