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Structure-Related Thermal Properties of Type-VII Clathrates SrNi2 P4 and BaNi2 P4 at Low Temperature

Novikov, Vladimir ; Pilipenko, Kirill ; Matovnikov, Aleksandr ; Mitroshenkov, Nikolay ; Plokhikh, Igor ; Tyablikov, Aleksandr ; Shevelkov, Andrey


Heat capacity C-P(T) (2-300K) and unit cell parameters a(T), b(T), and c(T) (5-300K) of type-VII clathrates SrNi2P4 and BaNi2P4 have been investigated experimentally. The studied compounds are prepared by a two-stage ampoule synthesis. Diffuse maxima of C-P(T) near 5K along with anomalies in temperature dependencies of unit cell parameters below 10K are observed and related to the influence of ...


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