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The Influence of β‐diiminato Ligands on As 4 Activation by Cobalt Complexes

Spitzer, Fabian ; Balázs, Gábor ; Graßl, Christian ; Keilwerth, Martin ; Meyer, Karsten ; Scheer, Manfred


In a systematic study of the activation of As-4, three [LCo(tol)] (L=beta-diiminato) complexes have revealed different steric and electronic influences. 2,6-Diisopropylphenyl (Dipp) and 2,6-dimethylphenyl (dmp) flanking groups were used, one of the ligands with H backbone substituents (beta-dialdiminate L-0) and two with Me substituents (beta-diketiminates L-3 and L-1). In the reaction with As-4, ...


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