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Reactivity of [{(N3N)W P] towards Gold(I) salts – Synthesis of [{(N3N)W P AuCl] and [{(N3N)W P}2Au][pftb] (pftb = Al(OC(CF3)3)4)

Balázs, Gábor ; Hautmann, Matthias ; Seidl, Michael ; Scheer, Manfred



Abstract

The reactivity of the terminal phosphido complex [(N3N)W equivalent to P] (1) (N3N = tren = N(CH2CH2NSiMe3)(3)) towards the coinage metal salts [Au(tht)Cl] (tht = tetrahydrothiophene) as well as [Au(MeCN)(4)](+)[pftb] containing the weakly coordinating anion [Al(OC{CF3)(3)}(4)] (pftb) was investigated. The complexes [{(N3N)W equivalent to P-AuCl] (2) as well as [{(N3N)W equivalent to ...

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