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Dicationic E4 Chains (E=P, As, Sb, Bi) Embedded in the Coordination Sphere of Transition Metals

Dütsch, Luis ; Fleischmann, Martin ; Welsch, Stefan ; Balázs, Gábor ; Kremer, Werner ; Scheer, Manfred


The oxidation chemistry of the complexes [{CpMo(CO)(2)}(2)(mu,eta(2):eta(2)-E-2)] (E=P (A), As (B), Sb (C), Bi (D)) is compared. The oxidation of A-D with [Thia](+) (=[C12H8S2](+)) results in the selective formation of the dicationic E-4 complexes [{CpMo(CO)(2)}(4)(mu(4),eta(2):eta(2):eta(2):eta(2)-E-4)](2+) (E=P (1), As (2), Sb (3), Bi (4)), stabilized by four [CpMo(CO)(2)] fragments. The ...


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