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Synthesis, crystal structure and physical properties of europium – manganese fluoride pnictides, EuMnPnF (Pn = P, As, Sb)

Plokhikh, I. V. ; Charkin, D. O. ; Verchenko, V. Yu. ; Kuznetsov, A. N. ; Tsirlin, A. A. ; Kazakov, S. M. ; Shevelkov, A. V.


The quaternary compounds EuMnPnF (Pn = P, As, Sb) have been prepared via solid state route at 1173 K, and their crystal and electronic structures as well as magnetic and transport properties have been elucidated. These compounds belong to the widespread LaAgSO structure type and crystallize in tetragonal (P4/nmm) unit cells with a = 4.0292(1) angstrom, c = 8.9505(2) angstrom for EuMnPF, a = ...


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