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Actinide-Pnictide (An−Pn) Bonds Spanning Non-Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi)

Rookes, Thomas M. ; Wildman, Elizabeth P. ; Balázs, Gábor ; Gardner, Benedict M. ; Wooles, Ashley J. ; Gregson, Matthew ; Tuna, Floriana ; Scheer, Manfred ; Liddle, Stephen T.



Abstract

The synthesis and characterisation is presented of the compounds [An(Tren(DMBS)){Pn(SiMe3)(2)}] and [An(Tren(TIPS)){Pn(SiMe3)(2)}] [Tren(DMBS)=N(CH2CH2NSiMe2But)(3), An=U, Pn=P, As, Sb, Bi; An=Th, Pn=P, As; Tren(TIPS)=N(CH2CH2NSiPr3i)(3), An=U, Pn=P, As, Sb; An=Th, Pn=P, As, Sb]. The U-Sb and Th-Sb moieties are unprecedented examples of any kind of An-Sb molecular bond, and the U-Bi bond is the ...

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