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Carbonylative Coupling of Alkyl Zinc Reagents with Benzyl Bromides Catalyzed by a Nickel/NN 2 Pincer Ligand Complex

Andersen, Thomas L. ; Donslund, Aske S. ; Neumann, Karoline T. ; Skrydstrup, Troels ; ;



Abstract

The reaction between a preassembled Cu-I bimetallic molecular clip with a short intermetallic distance and a series of fully aliphatic cyano-capped ditopic linkers with increasing lengths was investigated. It is shown that, depending on the length of the ditopic linkers, the rational design of unprecedented supramolecular compact metallacycles containing fully aliphatic walls is possible. The ...

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