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PPh3 Propeller Diastereomers: Bonding Motif PhPPh3 Face-On π-Ar in Half-Sandwich Compounds [(π-Ar)LL′MPPh3]

Brunner, Henri ; Balázs, Gábor ; Tsuno, Takashi ; Iwabe, Haruka


Chiral-at-metal compounds (R-Ru, S-C)/(S-Ru, S-C)-[CyRu(1O-2N) PPh3] PF6 and (R-Ru, S-C)/(S-Ru, S-C)-[CyRu(2O-1N) PPh3] PF6 were prepared using anions 1O-2N(-) and 2O-1N(-) of the Schiff bases, derived from the hydroxynaphthalde-hydes and (S)-1-phenylethylamine. The pure (R-Ru, S-C)-diastereomers were obtained by crystallization. In the unit cell of (R-Ru, S-C)-[CyRu(1O-2N) PPh3] PF6, there are ...


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