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NMR Properties of the Cyanide Anion, a Quasisymmetric Two-Faced Hydrogen Bonding Acceptor

URN to cite this document:
urn:nbn:de:bvb:355-epub-479251
DOI to cite this document:
10.5283/epub.47925
Shenderovich, Ilya G. ; Denisov, Gleb S.
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License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 01 Sep 2021 10:18


Abstract

The isotopically enriched cyanide anion, (13C≡15N)−, has a great potential as the NMR probe of non-covalent interactions. However, hydrogen cyanide is highly toxic and can decompose explosively. It is therefore desirable to be able to theoretically estimate any valuable results of certain experiments in advance in order to carry out experimental studies only for the most suitable molecular ...

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