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Dynamic Chelate Effect on the Li+-Ion Conduction in Solvate Ionic Liquids

Arai, Nana ; Watanabe, Hikari ; Yamaguchi, Tsuyoshi ; Seki, Shiro ; Ueno, Kazuhide ; Dokko, Kaoru ; Watanabe, Masayoshi ; Kameda, Yasuo ; Buchner, Richard ; Umebayashi, Yasuhiro


Lithium-glyme solvate ionic liquids (Li-G SILs), which typically consist of a lithium-ion (Li+) solvated by glymes of oligoethers and its counter anion, are expected as promising electrolytes for lithium secondary batteries. Additionally, a specific ligand-exchange Li+ conduction mechanism was proposed at the electrode/electrolyte interface of the cell using Li-G SILs. To reveal Li+ conduction in ...


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