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Compensation of London Dispersion in the Gas Phase and in Aprotic Solvents

Pollice, Robert ; Fleckenstein, Felix ; Shenderovich, Ilya ; Chen, Peter


The importance of London dispersion for structure and stability of molecules with less than about 200 atoms has been established in recent years but the quantitative understanding is still largely based on computations because of a persistent lack of suitable experimental data. We herein report a comprehensive computational and experimental study of the compensation of London dispersion in ...


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