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Highly selective metallogel from 4-biphenylcarboxy capped diphenylalanine and FeCl3

Sasmal, Supriya ; Maji, Krishnendu ; Díaz Díaz, David ; Haldar, Debasish


The gelation property of the iron(iii) complex of 4-biphenylcarboxy capped diphenylalanine (l-Phe-l-Phe, the hydrophobic core motif of Alzheimer's beta-amyloid polypeptide) has been reported. Gelation was observed selectively for FeCl3 and 4-biphenylcarboxy capped diphenylalanine, whereas Cd, Cu, Zn, Cr, Ni, Hg, Mg, Mn, Pb, and Pd complexes were not able to form a metallogel. However, Boc and ...


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