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Synthesis, crystal structure and photoluminescence of [NHEt3][Re(I)(quinaldate)(CO)3Cl]

Vogler, Arnd ; Hischa, Birgit ; Stempfhuber, Sabine


The salt [NHEt3]Re(I)(quinaldate)(CO)(3)Cl] was obtained by the reaction of Re(CO)(5)Cl with quinaldic acid and triethylamine in toluene. The crystal structure analysis of this salt revealed the presence of the complex anion [Re(quinaldate)(CO)(3)Cl] , with the d(6) Re(I) metal center in a pseudo-octahedral environment. The electronic spectra in absorption and emission exhibit bands which are ...


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