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Chirality in amino acids beyond the C α configuration

Brunner, Henri ; Tsuno, Takashi



Abstract

Based on a CSD search, a meta-analysis of 1179 structures of 19 natural amino acids H3NC alpha H(R)C '(O)O and their derivatives H3NC alpha H(R)C '(O)O(H/R/M), protonated, esterified, or coordinated at the carboxylic group, shows that the chirality chain with its two steps, established in the preceding paper for alanine, can be extended to natural amino acids. High diastereoselectivities are ...

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