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Selective distortion of the planar group C α C'(O)O to a chiral flat tetrahedron in the amino acid alanine

Brunner, Henri ; Tsuno, Takashi


Based on a Cambridge Structural Database (CSD) search, a meta-analysis of 116 structures of alanine H3NC alpha H(CH3)C '(O)O and its derivatives H3NC alpha H(CH3)C '(O)O(H/R/M), protonated, esterified, or coordinated at the carboxylic group, shows that in the first step of a chirality chain, the L configuration at C-alpha induces (M) and (P) conformations with respect to rotation around the ...


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