Go to content
UR Home

Trapping of a Highly Bent and Reduced Form of 2‐Phosphaethynolate in a Mixed‐Valence Diuranium–Triamidoamine Complex

Magnall, Rosie ; Balázs, Gábor ; Lu, Erli ; Tuna, Floriana ; Wooles, Ashley J. ; Scheer, Manfred ; Liddle, Stephen T.


The chemistry of 2-phosphaethynolate is burgeoning, but there remains much to learn about this ligand, for example its reduction chemistry is scarce as this promotes P-C-O fragmentations or couplings. Here, we report that reduction of [U(Tren(TIPS))(OCP)] (Tren(TIPS)=N(CH2CH2NSiPr3i)(3)) with KC8/2,2,2-cryptand gives [{U(Tren(TIPS))}(2){mu-eta(2)(OP):eta(2)(CP)-OCP}][K(2,2,2-cryptand)]. The ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons