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An Entry to Double Phosphanyl-Bridged Dinuclear Rhodium(II) Complexes

Böttcher, Hans-Christian ; Graf, Marion ; Mayer, Peter ; Scheer, Manfred


The reaction of [RhCp(coe)(2)] (1, coe = cis-cyclooctene) with one equivalent of the secondary phosphines PR2H in refluxing toluene afforded in situ the new complexes [RhCp(coe)(PR2H)] (R = Ph, 2a; R = o-tolyl, 2b; R = tBu, 2c) in good yields. Further thermolysis of 2a and 2b, respectively, in refluxing xylene resulted in the formation of the dinuclear doubly phosphanyl-bridged rhodium(II) ...


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