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Metal‐Assisted Opening of Intact P 4 Tetrahedra

Modl, Moritz ; Heinl, Sebastian ; Balázs, Gabor ; Delgado Calvo, Fuencisla ; Caporali, Maria ; Manca, Gabriele ; Keilwerth, Martin ; Meyer, Karsten ; Peruzzini, Maurizio ; Scheer, Manfred


The reactivity of ruthenium and manganese complexes bearing intact white phosphorus in the coordination sphere was investigated towards the low-valent transition-metal species [Cp ''' o] (Cp '''=eta(5)-C5H2-1,2,4-tBu(3)) and [(LM)-M-0] (L-0 = CH[CHN(2,6-Me2C6H3)] 2; M= Fe, Co). Remarkably, and irrespective of the metal species, the reaction proceeds by the selective cleavage of two P-P edges and ...


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