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Combined molecular dynamics (MD) and small angle scattering (SAS) analysis of organization on a nanometer-scale in ternary solvent solutions containing a hydrotrope

Schöttl, Sebastian ; Lopian, Tobias ; Prévost, Sylvain ; Touraud, Didier ; Grillo, Isabelle ; Diat, Olivier ; Zemb, Thomas ; Horinek, Dominik


Mixtures of three solvents, with two immiscible liquids and a third one miscible to both - the solvotrope, may exhibit structuration. We explore the phase diagram of n-octanol/ethanol/water, where ethanol is the hydrotrope, varying composition from the water-rich side to the n-octanol-rich side at constant ethanol fraction. We resolve nanometer-sized structures experimentally by mean of four ...


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