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Synthesis of 3-Oxo-2,3-dihydro-pyrrole Amino Acids as Chiral Dipeptidomimics

Maity, P. ; König, B.


We describe the synthesis of a novel chiral dipeptide β-sheet mimic based on aminomethyl-3-oxo-2,3-dihydropyrrole carboxylic acids. The synthesis uses a palladium-catalyzed allylation with the chiral Trost ligand as a key step for the construction of a quaternary chiral center. This allows the enantioselective conversion of 2-carboxy-3-hydroxy-pyrrole into ...


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