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Synthesis of 3-Oxo-2,3-dihydro-pyrrole Amino Acids as Chiral Dipeptidomimics

Maity, P. and König, B. (2006) Synthesis of 3-Oxo-2,3-dihydro-pyrrole Amino Acids as Chiral Dipeptidomimics. Synthesis (16), pp. 2719-2724.

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We describe the synthesis of a novel chiral dipeptide β-sheet mimic based on aminomethyl-3-oxo-2,3-dihydropyrrole carboxylic acids. The synthesis uses a palladium-catalyzed allylation with the chiral Trost ligand as a key step for the construction of a quaternary chiral center. This allows the enantioselective conversion of 2-carboxy-3-hydroxy-pyrrole into ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
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Keywords:pyrroles - 3-oxo-2,3-dihydropyrrole - allylations - amino acids - catalysis - palladium
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:49
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