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Recyclable Magnetic Microporous Organic Polymer (MOP) Encapsulated with Palladium Nanoparticles and Co/C Nanobeads for Hydrogenation Reactions

Stadler, Lisa ; Homafar, Maryam ; Hartl, Andreas ; Najafishirtari, Sharif ; Colombo, Massimo ; Zboril, Radek ; Martin, Petr ; Gawande, Manoj B. ; Zhi, Jian ; Reiser, Oliver



Abstract

Microporous organic polymers (MOPs) encapsulated with palladium nanoparticles (NPs) and immobilized on magnetic Co/C nanobeads show excellent activity in hydrogenation reactions of alkenes, alkynes, and nitro arenes with turnover frequencies (TOFs) up to 3000h(-1). The magnetic core of the nanobeads ensures an easy and fast recyclability for at least six consecutive runs by applying an external ...

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