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Amine‐Borane Dehydrogenation and Transfer Hydrogenation Catalyzed by α‐Diimine Cobaltates

Maier, Thomas M. ; Sandl, Sebastian ; Shenderovich, Ilya G. ; Jacobi von Wangelin, Axel ; Weigand, Jan J. ; Wolf, Robert


Anionic alpha-diimine cobalt complexes, such as [K(thf)(1.5){((Dipp)BIAN)Co(eta(4)-cod)}] (1; Dipp=2,6-diisopropylphenyl, cod=1,5-cyclooctadiene), catalyze the dehydrogenation of several amine-boranes. Based on the excellent catalytic properties, an especially effective transfer hydrogenation protocol for challenging olefins, imines, and N-heteroarenes was developed. NH3BH3 was used as a ...


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