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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-493379
- DOI to cite this document:
- 10.5283/epub.49337
This publication is part of the DEAL contract with Wiley.
Abstract
Reactions of di-tert-butyldiphosphatetrahedrane (1) with cycloocta-1,5-diene- or anthracene-stabilised metalate anions of iron and cobalt consistently afford complexes of the rarely encountered 1,2-diphosphacyclobutadiene ligand, which have previously been very challenging synthetic targets. The subsequent reactivity of 1,2-diphosphacyclobutadiene cobaltates toward various electrophiles has also ...

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