Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight

URN to cite this document:: urn:nbn:de:bvb:355-epub-493958
DOI to cite this document:: 10.5283/epub.49395

Rothfelder, Robin ; Streitferdt, Verena ; Lennert, Ulrich ; Cammarata, Jose ; Scott, Daniel J.

; Zeitler, Kirsten ; Gschwind, Ruth M.

; Wolf, Robert

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Date of publication of this fulltext: 14 Oct 2021 05:48

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Abstract

Detailed 31P{1H} NMR spectroscopic investigations provide deeper insight into the complex, multi-step mechanisms involved in the recently reported photocatalytic arylation of white phosphorus (P4). Specifically, these studies have identified a number of previously unrecognized side products, which arise from an unexpected non-innocent behavior of the commonly employed terminal reductant Et3N. The ...