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Synthesis of a Heterobimetallic Arsenic Triple-Decker Complex and Its Fragmentation Chemistry

Piesch, Martin ; Scheer, Manfred



Abstract

The synthesis of the metastable triple-decker complex [(Cp*Fe)(Cp'''Co)(mu,eta(5):eta(4)-As-5)] (3) (Cp* = pentamethyl-cyclopentadienyl, Cp''' = 1,2,4-tritertbutyl-cyclopentadienyl) is reported. 3 is sensitive toward thermal activation (and in solutions of acetonitrile), which converts 3 selectively into [(Cp*Fe)(Cp'''Co)(mu,eta(3):eta(3)-As-3)] (4) and [(Cp*Fe)(2)(Cp'''Co)(2) ...

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