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Structures and Chemical Bonding in Antimony(III) Bromide Complexes with Pyridine

Prokudina, Yana V. ; Davydova, Elena I. ; Virovets, Alexander ; Stöger, Berthold ; Peresypkina, Eugenia ; Pomogaeva, Anna V. ; Timoshkin, Alexey Y.


Weakly or "partially" bonded molecules are an important link between the chemical and van der Waals interactions. Molecular structures of six new SbBr3-Py complexes in the solid state have been determined by single-crystal X-ray diffraction analysis. In all complexes all Sb atoms adopt a pseudo-octahedral coordination geometry which is completed by additional Sb center dot center dot center dot ...


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