Synthesis‐Controlled Polymorphism and Optical Properties of Phyllosilicate‐Analogous Borosulfates M [B 2 (SO 4 ) 4 ] ( M =Mg, Co)

URN to cite this document:: urn:nbn:de:bvb:355-epub-496025
DOI to cite this document:: 10.5283/epub.49602

Netzsch, Philip

; Pielnhofer, Florian ; Glaum, Robert

; Höppe, Henning A.

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 11 Oct 2021 12:41

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Abstract

Increased synthetic control in borosulfate chemistry leads to the access of various new compounds. Herein, the polymorphism of phyllosilicate-analogous borosulfates is unraveled by adjusting the oleum (65 % SO3) content. The new polymorphs beta-Mg[B-2(SO4)(4)] and alpha-Co[B-2(SO4)(4)] both consist of similar layers of alternating borate and sulfate tetrahedra, but differ in the position of ...