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Magnesium bis(amidinate) and bis(guanidinate) complexes: impact of the ligand backbone and bridging groups on the coordination behaviour

Rösch, Andreas ; Schreiner, Simon H. F. ; Schüler, Philipp ; Görls, Helmar ; Kretschmer, Robert


A library of ten dinucleating bis(amidine) and bis(guanidine) ligands, in which the bridging groups, terminal rests, and backbone substituents were systematically altered, has been synthesized and subsequently applied in metallation reactions using three different magnesium sources. Eight Mg complexes could be isolated and fully characterized, and in seven cases their solid-state structure could ...


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