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Use of a cyclo-P4 building block – a way to networks of host–guest assemblies

Peresypkina, Eugenia ; Bielmeier, Martin ; Virovets, Alexander ; Scheer, Manfred



Abstract

Despite the proven ability to form supramolecular assemblies via coordination to copper halides, organometallic building blocks based on four-membered cyclo-P-4 ligands find only very rare application in supramolecular chemistry. To date, only three types of supramolecular aggregates were obtained based on the polyphosphorus end-deck complexes (CpTa)-Ta-R(CO)(2)(eta(4)-P-4) (1a: Cp-R = Cp ''; 1b: ...

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