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A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization

Yadav, Ravi ; Goswami, Bhupendra ; Simler, Thomas ; Schoo, Christoph ; Reichl, Stephan ; Scheer, Manfred ; Roesky, Peter W.



Abstract

Pentaphosphaferrocene, [Cp*Fe(eta(5)-P-5)] (Cp* = eta(5)-C5Me5), was used as a polyphosphorus source to obtain germylene-polyphosphide complexes. A stepwise reactivity was observed between the di-germylene, [LGe-GeL] (L = {PhC((NBu)-Bu-t)(2)}), and [Cp*Fe(eta(5)-P-5)]. Firstly, reductive homolytic cleavage of the Ge-Ge single bond in [LGe-GeL] led to [(LGe)(2){(mu,eta(4)-P-5)FeCp*}]. This complex showed an unprecedented isomerization.


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