Go to content
UR Home

A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization

Yadav, Ravi ; Goswami, Bhupendra ; Simler, Thomas ; Schoo, Christoph ; Reichl, Stephan ; Scheer, Manfred ; Roesky, Peter W.


Pentaphosphaferrocene, [Cp*Fe(eta(5)-P-5)] (Cp* = eta(5)-C5Me5), was used as a polyphosphorus source to obtain germylene-polyphosphide complexes. A stepwise reactivity was observed between the di-germylene, [LGe-GeL] (L = {PhC((NBu)-Bu-t)(2)}), and [Cp*Fe(eta(5)-P-5)]. Firstly, reductive homolytic cleavage of the Ge-Ge single bond in [LGe-GeL] led to [(LGe)(2){(mu,eta(4)-P-5)FeCp*}]. This complex showed an unprecedented isomerization.

Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons