Go to content
UR Home

Phosphorus Analogues of [Ni(bpy)2]: Synthesis and Application in Carbon–Halogen Bond Activation

Leitl, J. ; Coburger, P. ; Scott, D. J. ; Ziegler, C. G. P. ; Hierlmeier, G. ; Wolf, R. ; van Leest, N. P. ; de Bruin, B. ; Hörner, G. ; Müller, C.



Abstract

The neutral, homoleptic pyridylphosphininenickel(0) complex [Ni(2-Py-4,6-Ph (2)-PC5H2)(2)] (1) has been obtained by reaction of the formal Ni(0) source [(IPONi(H2C=CHSiMe3)(2)] with 2 equiv of 2-(2'-pyridyl)-4,6-diphenylphosphinine (L). Compound 1 can be oxidized both electrochemically and through the use of ferrocenium salts, to afford the corresponding Ni(I) complexes [1]BF4, [1 (THF)]PF6, and ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons