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Normal to abnormal ItBu·AlH3 isomerization in solution and in the solid state

Chernysheva, Anna M. ; Weinhart, Michael ; Scheer, Manfred ; Timoshkin, Alexey Y.


A complex of an N-heterocyclic carbene (IBu)-Bu-t (1,3-di-tert-butylimidazolin-2-ylidene) and aluminum hydride was observed to isomerize into an abnormal carbene complex aItBu center dot AlH3 (aI(t)Bu = 1,3-ditert-butylimidazolin-4-ylidene) in a polar solvent, and, for the first time, in the solid state. (IBu)-Bu-t center dot AlH3 and aItBu center dot AlH3 were structurally characterized by ...


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