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Highly Selective Substitution and Insertion Reactions of Silylenes in a Metal-Coordinated Polyphosphide

Yadav, Ravi ; Simler, Thomas ; Reichl, Stephan ; Goswami, Bhupendra ; Schoo, Christoph ; Köppe, Ralf ; Scheer, Manfred ; Roesky, Peter W.


Selective substitution and insertion reactions of silylenes into the cyclo-P, ring of [Cp*Fe(eta(5)-P-5)] are reported. The selective substitution of one P atom by an isoelectronic [LSi] fragment (L = PhC((NBu)-Bu-t)(2)) leads to [(eta(4)-P4SiL)FeCp*] and [LSi(Cl)=P-SiL(Cl)(2)]. To elucidate the reaction mechanism, [{LSi(N(SiMe3)(2))}{(eta(4)-P-5)FeCp*}], in which the silicon atom binds to the ...


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