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Structures of molecular complexes of SbCl5 with pyridine and acetonitrile: equal bond lengths, different stability

Davydova, E. I. ; Virovets, A. V. ; Peresypkina, E. V. ; Kazakov, I. V. ; Timoshkin, A. Yu.


Molecular structure of crystalline complex SbCl5 center dot Py was determined for the first time and the structure of the complex SbCl5 center dot AN was refined by means of single crystal X-ray diffraction analysis. It is shown that donor-acceptor Sb-N bond lengths for these complexes are equal within the experimental error. Quantum chemical calculations of the complexes in the gas phase reveal ...


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