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Lateral Force Microscopy Reveals the Energy Barrier of a Molecular Switch

Weymouth, Alfred J. ; Riegel, Elisabeth ; Simmet, Bianca ; Gretz, Oliver ; Giessibl, Franz J.



Zusammenfassung

Copper phthalocyanine (CuPc) is a small molecule often used in organic light emitting diodes where it is deposited on a conducting electrode. Previous scanning tunneling microscopy (STM) studies of CuPc on Cu(111) have shown that inelastic tunneling events can cause CuPc to switch between a ground state and two symmetrically equivalent metastable states in which the molecule is rotated. We ...

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