Conversion of E 4 (E 4 =P 4 , As 4 , AsP 3 ) by Ni(0) and Ni(I) Synthons – A Comparative Study - University of Regensburg Publication Server

URN to cite this document:: urn:nbn:de:bvb:355-epub-510747
DOI to cite this document:: 10.5283/epub.51074

Haimerl, Maria ; Graßl, Christian ; Seidl, Michael ; Piesch, Martin ; Scheer, Manfred

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Date of publication of this fulltext: 02 Dec 2021 06:32

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Abstract

The reactivity of white phosphorus and yellow arsenic towards two different nickel nacnac complexes is investigated. The nickel complexes [(L1Ni)2tol] (1, L1=[{N(C6H3iPr2-2,6)C(Me)}2CH]−) and [K2][(L1Ni)2(μ,η1 : 1-N2)] (6) were reacted with P4, As4 and the interpnictogen compound AsP3, respectively, yielding the homobimetallic complexes [(L1Ni)2(μ-η2,κ1:η2,κ1-E4)] (E=P (2 a), As (2 b), AsP3 ...