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Conversion of E 4 (E 4 =P 4 , As 4 , AsP 3 ) by Ni(0) and Ni(I) Synthons – A Comparative Study

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Haimerl, Maria ; Graßl, Christian ; Seidl, Michael ; Piesch, Martin ; Scheer, Manfred
License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 02 Dec 2021 06:32

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The reactivity of white phosphorus and yellow arsenic towards two different nickel nacnac complexes is investigated. The nickel complexes [((LNi)-Ni-1)(2)tol] (1, L-1=[{N((C6H3Pr2)-Pr-i-2,6)C(Me)}(2)CH](-)) and [K-2][((LNi)-Ni-1)(2)(mu,eta(1 : 1)-N-2)] (6) were reacted with P-4, As-4 and the interpnictogen compound AsP3, respectively, yielding the homobimetallic complexes ...


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