[ A ([18]crown‐6)] 2 [Pt(CO) 3 ] ⋅ 10 NH 3 ( A =K, Rb) – A crystal structure containing the long postulated [Pt(CO) 3 ] 2− - University of Regensburg Publication Server

URN to cite this document:: urn:nbn:de:bvb:355-epub-515915
DOI to cite this document:: 10.5283/epub.51591

Tiefenthaler, Susanne M. ; Kleemiss, Florian

; Korber, Nikolaus

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Date of publication of this fulltext: 08 Feb 2022 06:36

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Abstract

The compound [A([18]crown-6](2)[Pt(CO)(3)] . 10 NH3 (A=K, Rb, [18]crown- 6=1,4,7,10,13,16-Hexaoxacyclooctadecane) containing the anion [Pt(CO)(3)](2-) was the unexpected result of a reaction between K6Rb6Ge17, Pt(CO)(2)(PPh3)(2), [18]crown-6 and [2.2.2]-crypt. This compound represents the first example of a mononuclear carbonyl platinate and expands the list of known group 10 carbonyl metallates. ...