Palladium-catalyzed ring opening of fused bicyclic vinylcyclopropanes

URN to cite this document:: urn:nbn:de:bvb:355-epub-516893
DOI to cite this document:: 10.5283/epub.51689

Wurzer, Nikolai

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Date of publication of this fulltext: 13 Feb 2023 08:11

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Item type:	Thesis of the University of Regensburg (PhD)
Open Access Type:	Primary Publication
Date:	13 February 2023
Referee:	Prof. Dr. Oliver Reiser
Date of exam:	4 February 2022
Institutions:	Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Keywords:	Cyclopropanes, Palladium, Heck, Ring Opening, Heterocycles
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Yes
Item ID:	51689

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Abstract (English)

The present PhD thesis demonstrates the further development of the endocyclic ring opening of cyclopropanated bicycles/fused bicycles which has first been described in 2019 by Reiser and co-workers who demonstrated that this strategy allows for a facile access to highly sub- stituted, arylated dihydropyridines and 2H-pyrans. In particular, this thesis improved upon the overall efficiency of the ...

Translation of the abstract (German)

Die vorliegende Dissertation behandelt die Weiterentwicklung der endozyklischen Ringöffnung cyclopropanierter Bizyklen/anellierter gespannter Ringsysteme. Die erstmals im Jahr 2019 von Reiser und Mitarbeitern beschrieben Strategie, welche einfachen Zugang zu hoch- substituierten, arylierten Dihydropyridinen und 2H-Pyranen ermöglicht, wurde hinsichtlich ihrer Effizienz, sowie ihrer Substratvielfalt sowohl für Cyclopropane als auch für Kupp- lungsreagenzien verbessert.

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