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Palladium-catalyzed ring opening of fused bicyclic vinylcyclopropanes
Wurzer, Nikolai (2023) Palladium-catalyzed ring opening of fused bicyclic vinylcyclopropanes. PhD, Universität Regensburg.Date of publication of this fulltext: 14 Nov 2023 14:23
Thesis of the University of Regensburg
DOI to cite this document: 10.5283/epub.54992
This is the latest version of this item.
Abstract (English)
The present PhD thesis demonstrates the further development of the endocyclic ring opening of cyclopropanated bicycles/fused bicycles which has first been described in 2019 by Reiser and co-workers who demonstrated that this strategy allows for a facile access to highly sub- stituted, arylated dihydropyridines and 2H-pyrans. In particular, this thesis improved upon the overall efficiency of the ...
The present PhD thesis demonstrates the further development of the endocyclic ring opening of cyclopropanated bicycles/fused bicycles which has first been described in 2019 by Reiser and co-workers who demonstrated that this strategy allows for a facile access to highly sub- stituted, arylated dihydropyridines and 2H-pyrans. In particular, this thesis improved upon the overall efficiency of the process as well as increased the substrate diversity both for cyclopropanes as well as coupling reagents.
Translation of the abstract (German)
Die vorliegende Dissertation behandelt die Weiterentwicklung der endozyklischen Ringöffnung cyclopropanierter Bizyklen/anellierter gespannter Ringsysteme. Die erstmals im Jahr 2019 von Reiser und Mitarbeitern beschrieben Strategie, welche einfachen Zugang zu hoch- substituierten, arylierten Dihydropyridinen und 2H-Pyranen ermöglicht, wurde hinsichtlich ihrer Effizienz, sowie ihrer Substratvielfalt sowohl für Cyclopropane als auch für Kupp- lungsreagenzien verbessert.
Involved Institutions
Details
| Item type | Thesis of the University of Regensburg (PhD) |
| Date | 13 February 2023 |
| Referee | Prof. Dr. Oliver Reiser |
| Date of exam | 4 February 2022 |
| Institutions | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Keywords | Cyclopropanes, Palladium, Heck, Ring Opening, Heterocycles |
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences |
| Status | Published |
| Refereed | Yes, this version has been refereed |
| Created at the University of Regensburg | Yes |
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-549924 |
| Item ID | 54992 |
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