Reactivity of the stibinidene complex [ClSb{Cr(CO) 5 } 2 (thf)]

URN to cite this document:: urn:nbn:de:bvb:355-epub-518105
DOI to cite this document:: 10.5283/epub.51810

Rummel, Lena ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred

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Date of publication of this fulltext: 24 Feb 2022 11:28

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Abstract

Stibinidene complexes are rare and highly sensitive low-valent main group compounds, which have not been studied extensively for their reaction behavior so far. In the reaction with GaCl3, the stibinidene complex [ClSb{Cr(CO)5}2(thf)] (1) shows a dimerization to [ClSb{Cr(CO)5}2]2 (2) and yields the anionic double-chlorinated compound [Cl2Sb{Cr(CO)5}2]− (3) in the reaction with different ionic ...