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Reactivity of the stibinidene complex [ClSb{Cr(CO) 5 } 2 (thf)]

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Rummel, Lena ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred
License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 24 Feb 2022 11:28

This publication is part of the DEAL contract with Wiley.


Stibinidene complexes are rare and highly sensitive low-valent main group compounds, which have not been studied extensively for their reaction behavior so far. In the reaction with GaCl3, the stibinidene complex [ClSb{Cr(CO)(5)}(2)(thf)] (1) shows a dimerization to [ClSb{Cr(CO)(5)}(2)](2) (2) and yields the anionic double-chlorinated compound [Cl2Sb{Cr(CO)(5)}(2)](-) (3) in the reaction with ...


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